Synchro/proshift/slickshift/dogring, I've driven them all on the street and did all the conversions myself. Here's my feelings on the subject...
Synchros-
If you plan to shift at hi revs, oil can be too slick and clutch discs can be too heavy for a synchro to do it's job quickly. The synchro cone needs to grab the gear which also means the clutch disc needs to be slowed down as well before the gearchange can be accomplished. Using a gear oil that has EP additives can really slow the process down.
Pro-shift / "slick-shift"-
Basically the same thing, opening up the "window" between the engagement lugs, making it easier to complete the shift at high speeds. Many transmissions have 30 engagement lugs, allowing removal of every other lug (and every other corresponding internal slider spline). The engagement window is about 200% bigger, and much easier to hit at speed. The number of lugs is reduced, so those that remain get a lot more wear and tear. For really high RPM applications that don't have a lot of torque, sometimes 2 out of 3 of the 30 lugs/splines are removed for an even larger engagement window. This all works great for high speed shifting, but normal wear/tear or even one clutch screwup can burr over the internal splines in a slider, now the slider won't go over the lugs or the slider splines won't slide into the splines on it's hub. The only fix is complete dis-assembly to dress up the burrs or replace parts. There is no provision to speed-up or slow down the clutch disc ("synchronize" input shaft speed with the rest of the geartrain), so all shifts come with a harsh clunk or bang unless the driver matches RPM before completing the shift. A side effect of this larger engagement window is increased lash in the drivetrain, leading to less refined manners on the street.
Pro-Shift is a bit better as the stock gear lugs are replaced with much more robust parts to regain some of the lost strength of removing lugs. They can also be re-sharpened many times before needing replacement, but one missed shift can burr things up, requiring frequent maintenance.
Faceplate-
Completly different design for opening up the engagement window that spreads the wear/tear over much more area. Any burrs are self-removing, and a slight angle on the engagement faces help "pull" the parts together for even quicker shifts. It's almost impossible to miss a gear. Even bumping the shifter with the engine idling just sitting in the driveway can result in sudden engagement of the drivetrain. The hardest part of a shift is pulling the trans out of the gear that it's currently in, as the slight angle on the engagement faces pulls them together while they are transmitting power. Removing torque by using the clutch (or even just a slight reversal of torque without using the clutch) is all that is needed to start a shift, completing the rest of the shift can happen almost instantly, without further thought. Simply placing a slight pre-load on the shifter while the engine bounces off of a rev limiter is enough to complete a shift without using a clutch. Without rev-matching engagement can be very harsh, so a good driver can make all the difference between winning a race or getting a DNF on a road course. For drag racing, the magic formula for survival of the drivetrain is in the clutch.
I've had them all on the street. I would not recommend the Pro-Shift type mods, just too much maintenance. If you go with the Dog Rings, I would recommend that you keep a synchro on 1st gear, as it allows you to easily slip the trans into gear with the engine running. Without a synchro, you almost have to start the car in gear to avoid the nasty clunk.
Here's a link to the most informative thread I've ever came across on the subject with regard to explaning the differences... synchro/proshift/faceplate info w/ pictures (i'm "granny" on that thread)
GRM really needs to do an article on the subject. Lots of people in the auto world have heard of proshift/dogrings/faceplating, but very few seem to actually know what they are. There are shops that do this kind of work, but it can be done at home with the right set of tools.