I start by sauteing half of a large white onion (chopped), as many garlic cloves as you want (sliced), 8 serrano peppers (chopped), 4 jalepeno peppers (chopped), and 2 habenero peppers (chopped.)
ONLY sautee until just barely starting to get soft. This is important.
Add 1.5 cups of beef or chicken broth/stock. Small can of tomato paste. Large can crushed tomatoes. Tons of chili powder, some cumin, white, black, cayenne,and crushed red pepper, touch of cinnamon. Mix.
Add your beans (I like a mix. Black, red kidney, etc.. whatever i've got laying around) and any canned veggies you might add. (I drain and rinse a can of hominy and throw it in. Sometimes a small can of sliced black olives if i'm feeling sassy.)
Once everything is up to temp, very light simmer, i then add 4-5lbs of cubed beef that i previously browned. Whatever cut is on sale/cheap that day. It's going to cook forever, i don't care about putting prime rib or whatever in my chili. Usually just a bulk pack of stew beef, because that's all chili really is: Garbage Stew. At this point, i also crumble and dump in about 5-6 slices of bacon i cooked earlier for some smokey-ness.
Stir. Return to slow simmer. At this point, add any other fresh veggies you might want/need. (I get fancy and weird and will sautee portabello mushroom chunks in red wine, then throw them in.)
Let it cook forever. I usually cook on low heat for a good 4-5 hours minimum. Makes a huge amount, it's great heated up, it's good on cornmeal waffles topped with cheese and thrown under the broiler for a minute, it's damn near good cold. Eat 3/4ths of it, throw the remaining 1/4 in the freezer for when you need a chili fix down the road.
Random pics from last batch. I actually make a "His" and a "Hers" batch because SWMBO doesn't like hers quite as spicy and prefers ground beef and beans, none of the weird stuff.
Random ingredients:
The "Holy Trinity" with a twist:
Adding stock and tomato paste:
Browning beef. The stew meat is usually a little fatty so i tend to brown in 1 pound "batches" now.
Sauteing/steaming portebellos in red wine:
All together now (pre-beans):